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Q.

The formation of  PH4+  is difficult compared to NH4+  because:

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a

lone pair of  phosphorus is optically inert

b

lone pair of  phosphorus resides at  sp3  orbital  

c

lone pair of  phosphorus resides in almost pure s-orbital

d

lone pair of  phosphorus resides in almost pure p-orbital

answer is D.

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Detailed Solution

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According to Drago's rule lone pair on phosphorus resides in almost pure s-orbital, hence due to non-directional nature, its overlapping tendency is greatly reduced in comparison to a lone pair present in hybrid orbital, which is directional as present in  N¯H3.

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