Q.

The formation of phosgene is represented as,  COg+Cl2 gCOCl2g. The reaction is carried out in 500mL flask. At equilibrium 0.3 mole of phosgene, 0.1 mole of CO and 0.1 mole of Cl2  are present. The equilibrium constant of the reaction is

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a

15

b

6

c

3

d

5

answer is B.

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Detailed Solution

COg+Cl2g  COCl2 g
At eq. 

0.1mole  0.1 mole    0.3 mole
C=nv    0.10.5             0.10.5             0.30.5
Kc=COCl2COCl2=0.30.5×0.50.1×0.50.1=15

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