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Q.

The formation of the oxide ion O2(g) from oxygen atom requires first an exothermic and then an endothermic step as shown below:
 O(g)+eO(g);ΔH0=141kJ  mol1
 O(g)+eO2(g);ΔH0=+780kJ  mol1
Thus process of formation of O2 in gas phase is unfavourable even though O2 is isoelectronic with neon. It is due to the fact that,

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a

O ion has comparatively smaller size than oxygen atom.

b

oxygen is more electronegative.

c

addition of electron in oxygen results in larger size of the ion.

d

electron repulsion outweighs the stability gained by achieving noble gas configuration.

answer is C.

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Detailed Solution

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Stability due to octet is outweighed by electron repulsions

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