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Q.

The formation of the oxide ion O2-(g) requires first an exothermic and then an endothermic step shown below

O(g)+e=O(g); ΔHeg=142kJmol1

O(g)+e=O2(g); ΔHef=+844kJmol1

This is because:

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a

Oxygen is more electronegative

b

O-ion will tend to resist the addition of another electron of account of same charge,

c

O- ion baa comparatively larger size than oxygen atom.

d

Oxygen has high electron affinity 

answer is A.

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Detailed Solution

Due to strong e e e repulsion in small sized O- ion, O- ion has a tendency to reject the addition of another electron. In order to overcome this repulsive force, energy is needed.

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The formation of the oxide ion O2-(g) requires first an exothermic and then an endothermic step shown belowO(g)+e−=O−(g); ΔHeg=−142kJmol−1O−(g)+e−=O2−(g); ΔHef=+844kJmol−1This is because: