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Q.

The formation of the oxide ion, O(g)2from oxygen atom requires first an exothermic andthen an endothermic step as shown below

 O(g)+eO(g);ΔegH1=141kJmol1 O(g)+eO(g)2;ΔegH1=+780kJmol1

Thus process of formation of O–2 in gas phase is unfavourable even though O–2 is isoelectronic with Neon. It is due to the fact that

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a

Oxygen is more electronegative

b

Addition of electron in oxygen results in larger size of the atom

c

Electron repulsion outweighs the stability gained by achieving noble gas configuration

d

O ion has comparatively smaller size than oxygen atom

answer is C.

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Detailed Solution

Given, an exothermic step must come first, followed by an endothermic step, to produce the oxide ion, O2-(g), from an oxygen atom:

O(g)+e-O-(g);ΔfH=-141 kJ mol-1

O-(g)+e-O2-(g);ΔfH=+780 kJ mol-1

Despite the fact that O2-and neon have identical electron configurations, the process of O2-formation in the gas phase is unfavorable. because the stability gained by achieving a noble gas configuration is outweighed by the electron repulsion.

The electrostatic attraction between the two negative charges is very strong when an electron is added to an O- anion. As a result of this, it is observed that the second electron gain enthalpy is positive for oxygen. 

Therefore, option(C) is the answer.

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