Q.

The formation of O2+PtF6 is the basis for the formation of xenon fluorides. This is because:

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a

Oand Xe have comparable sizes.

b

Both Oand Xe are gases.

c

Oand Xe have comparable electronegativities. 

d

O2 and Xe have comparable ionisation energies. 

answer is C.

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Detailed Solution

In March 1962, Neil Bartlett, then at the University of British Columbia, observed the reaction of a noble gas. First, he prepared a red compound which is formulated as O2+PtF6 and it is already know that the first ionisation enthalpy of molecular oxygen (1175 kJ mol-1) is almost similar with that xenon (1170 kJ mol-1). Then he made efforts to prepare same type of compound by mixing Pt F6 and Xenon Xe+PtF6+. After this discovery, a number of xenon compounds mainly with most electronegative elements like fluorine and oxygen, have been synthesised. 

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