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Q.

The forward reaction rate for the nitric oxide-oxygen reaction

2NO+O22NO2 has the rate law as:

 Rate =k[NO]2O2

If the mechanism is assumed to be:

2NOeegN2O2 (rapid equilibration)

N2O2+O2k22NO2 (slow step) 

then which of the following is(are) correct?

I. Rate constant = keq k2

II. N2O2=keq[NO]2

III. N2O2=keq[NO]

IV.  Rate constant =k2

The correct option is

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a

None of these 

b

I, III

c

III, IV

d

I, II

answer is D.

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Detailed Solution

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keq=N2O2[NO]2N2O2=keq [NO]2 and  RDS: Rate =k2N2O2O2=k2keq[NO]2O2=k[NO]2O2

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