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Q.

The freezing point depression of 0.001 m Kx[Fe(CN)6] is 7.10×103 K. Determine the value of x. Given, Kf=1.86 K kg mol1 for water 

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a

2

b

3

c

4

d

5

answer is A.

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Detailed Solution

Δx=i×Kf×m7.10×103=i×1.86×0.001i=3.817α=i1n11=3.8171(x+1)1x=2.817=3

 Molecular formula of the compound is 

K3[Fe(CN)6]

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The freezing point depression of 0.001 m Kx[Fe(CN)6] is 7.10×10−3 K. Determine the value of x. Given, Kf=1.86 K kg mol−1 for water