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Q.

The freezing point of a solution containing 0.2g of acetic acid in 20.0g benzene is lowered by 0.45°C. The degree of association of acetic acid in benzene is ________ (nearest integer)
(Assume acetic acid dimerises in benzene and Kf for benzene =5.12  K kg mol-1)
Mobserved  of acetic acid =113.78

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answer is 95.

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Detailed Solution

Given, Ws=0.2g, Wo=20g Tf=iKfm i=1-α+α2=1-α2 m=WsMol. wt.×1000Wo Tf=(1-α2)5.12×0.260×100020 α=0.946 The degree of association=94.6%95%

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