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Q.

The freezing point of a solution containing 28.335 cm3 of ethylene glycol in 50 gm water is found  to be –34°C. Assuming ideal behaviour, calculate the density of ethylene glycol in g/ml. Kf for water 1.86 k kg mol–1.

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answer is 2.

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Detailed Solution

ΔTf=Kf×m=Kf×WAMA×1000WBWA=34×62×501.86×1000=56.66d=WAV=56.66628.335=2

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