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Q.

The freezing point of a solution containing 36 g of a compound (empirical formula: CH2O) in 1.20 kg of water is found to be - 0.93 °C. The molecular formula of the solute is

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a

CH2O

b

C2H4O2

c

C3H6O3

d

C4H8O4

answer is B.

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Detailed Solution

-ΔTf=Kfm0.93 K=1.86 K kg mol-136 g/M1.20 kg

This gives M=1.86×360.93×1.20 g mol-1=60 g mol-1

n= Molar mass  Molar Empirical formula mass =60 g mol-130 g mol-1=2

Hence, molecular formula is C2H4O2

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