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Q.

The freezing point of an aqueous solution of 0.1m Hg2 Cl2 will be: (If Hg2Cl2 is 80% ionized in the solution to give Hg22+ and Cl-)

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a

0.42 Kf

b

-0.26 Kf

c

-4.2 Kf

d

-2.6 Kf

answer is A.

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Detailed Solution

α=i1n10.8=i131=2.6ΔTf=ifm2.6×Kf×0.1

Tf° - Tf = 0.26Kf

Tf = 0 -0.26Kf = - 0.26Kf

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