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Q.

The frequency of light emitted for the transition n = 4 to n = 2 of He+  is equal to the transition in H atom corresponding to which of the following?                                                                 

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a

n = 3 to n = 1

b

n = 2 to n = 1

c

n = 3 to n = 2

d

n = 4 to n = 3

answer is B.

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Detailed Solution

v=RZ2(1n121n22)

For    He+,Z=2,n1=2,n2=4

v=R(2)2[122142]

=4R[316]                                       .......(i)

=3R4

For H, Z = 1 as the frequency of light emitted for the transition n = 4 to n =2 of  He+ is equal to the transition in H – atom corresponds to n = 2 to n = 1

v=R(1)2[112122]

=R[34]=3R4

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