Q.

The function of fluorspar in the electrolytic reduction of alumina dissolved in fused cryolite (Na3AlF6) is:

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a

as a catalyst

b

to lower the temperature of the melt and improve the conductivity of cell

c

to decrease the rate of oxidation of carbon at the  anode

d

to decrease the rate of oxidation of carbon at the cathode

answer is B.

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Detailed Solution

CaF2andNa3AlF6 are added to decrease the MP of electrolyte and increase the conductivity of cell. 

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The function of fluorspar in the electrolytic reduction of alumina dissolved in fused cryolite (Na3AlF6) is: