Q.

The gas phase reaction, 2A(g)A2(g) at 400K has  ΔG0=+25.2KJmol1 The equilibrium constant Kc for this reaction is _____ ×102

[Use: R=8.3Jmol1K1,ln10=2.3,log102=0.30,1atm=1bar]

[antilog 0.3=0.501]

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answer is 166.

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Detailed Solution

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As the reaction is in gaseous phase,

ΔG0=+25.2kJ/mol1

So, Kpwill be calculated from equation,

ΔG0=2.303RTlogKp

25.2×1000Jmol=2.303×8.3JmolK×400K×logKp

logKp=25.2×10002.303×8.3×400=3.30

Kp=103.30;Kp=100.30×103;Kp=0.501×103

Kp=5.01×104;Kp=Kc(RT)Δng

5.01×104=Kc8.3×4001

Kc=5.01×104×8.3×400=166.3×102166×102

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The gas phase reaction, 2A(g)⟹A2(g) at 400K has  ΔG0=+25.2KJ mol−1 The equilibrium constant Kc for this reaction is _____ ×10−2[Use: R=8.3J mol−1K−1,ln10=2.3,log102=0.30,1atm=1bar][antilog −0.3=0.501]