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Q.

The gas A2 in the left gass bulb allowed to react with gas B2 present in right glass bulb as shown in figure : 

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A2g  +B2g     2ABgKC = 4 at 27C what is the concentration of AB when equilibrium is established.

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a

1.33 M

b

2.66 M

c

0.66 M

d

0.33 M

answer is C.

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Detailed Solution

              A2 + B2    2AB At t=0,  2        4                 0 at equi.  2-x   4-x           2x

where, x=degree of dissociation

con  = nV                    V = 1 + 3 = 4

A2 = 2-x4   B2 =4-x4     AB = 2x4=x2

 

KC= x222-x44-x4=x2 × 4 × 44 × 2-x4-x

KC=  x2 ×  48-6x  + x2KC = 4

4 = x2 × 48-6x + x2

x2 = 8  6x + x2

6x = 8    x = 43

AB = x2=43 × 2 = 0.66

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