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Q.

The gaseous phase reaction A(g)2 B( g)+C(g) is first order with respect to A. If the reaction is started with pressure p0 of A, then the pressure pt of the system at time t is given by the expression

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a

ln3p0-pt2p0=-kt

b

ln3p0-pi2p0=-kt

c

pt-p0p0=-kt

answer is A.

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Detailed Solution

A(g)p0-p2B(g2p)+C(g)p

pt=p0p+2p+p=p0+2pln[A][A]0=ktlnp0pp0=kt lnp0ptp0/2p0=ktln3p0pt2p0=kt

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