Q.

The general formula of an ionic compound crystallizing in antifluorite structure is

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a

AB3

b

AB

c

AB2

d

A2B

answer is C.

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Detailed Solution

The general formula of an ionic compound crystallizing in antifluorite structure is A2B.

Cations and anions are arranged in the anti-fluorite structure in the opposite direction from the fluorite structure. 

 The structure of Na2O is an antifluorite. I The O-2 ions form a cubic close-packed lattice (fcc structure) in the crystal structure of Na2O, while the Na+ ions fill all of the tetrahedral spaces.

(ii) There are 8 Na+ ions in contact with each oxide ion, O-2 ion, and 4 oxide ions with each Na+ ion.Na2O has 4:8 coordination as a result.

Na2S are  example.

Hence the option C is correct. 

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