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Q.

The geometry and magnetic behavior of the complex [Ni(CO)4] are

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a

tetrahedral geometry and paramagnetic

b

square planar geometry and diamagnetic

c

square planar geometry and paramagnetic

d

tetrahedral geometry and diamagnetic

answer is B.

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Detailed Solution

Let oxidation state of Ni be : 'x'.
Oxidation state of Ni in [Ni(CO)4] can be calculated as:
x + 4(0) = 0, giving x = 0.
Therefore, oxidation state of Ni in [Ni(CO)4] is 0, giving its configuration to be 3d84s2. 
CO pairs unpaired 3d electrons because it is a strong field ligand. Additionally, it leads to a transfer of the 4S electrons into the 3d orbital, resulting in sp3 hybridization and the formation of the tetrahedral structure.
[Ni(CO)4] is diamagnetic since there aren't any unpaired electrons in this situation.
Hence, the correct option is option (B) tetrahedral geometry and diamagnetic.

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