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Q.

The geometry and magnetic behaviour of the complex [Ni(CO)4] are 

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a

Tetrahedral geometry and diamagnetic

b

Square planar geometry and diamagnetic

c

Square planar geometry and paramagnetic

d

Tetrahedral geometry and paramagnetic

answer is B.

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Detailed Solution

Ni(28):[Ar]3d84s2

 CO is a strong field ligand, so unpaired electrons get paired. Hence, configuration would

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For, four 'CO' ligands hybridisation would be sp3 and thus the complex would be diamagnetic and of tetrahedral geometry.

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