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Q.

The geometry of the compound [Pt(NH3)2Cl2] is

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a

Tetrahedral

b

Square planar

c

Pyramidal

d

Octahedral

answer is A.

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Detailed Solution

[Pt (NH3)2Cl2] is a square planar complex.

Pt has oxidation state of +2 and configuration is [Xe]5d8. Because of pairing, four of the 5d orbitals of Pt are doubly occupied by the 8 electrons. One empty 5d orbital, one 6s orbital and two 5p orbitals accommodate electrons donated by the two ammine and two chloro ligands. Hybridization of the complex becomes dsp2.

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