Q.

The geometry of Ni(CN)42 and NiCl42 ions are :

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a

square planar, tetrahedral respectively

b

tetrahedral

c

tetrahedral and square planar respectively

d

square planar

answer is C.

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Detailed Solution

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(NiCl4) 2- Cl is weak field ligand which doesn't help in pairing of electron and thus nickel has 2 unpaired electron left due to which it becomes paramagnetic and its configuration is sp3 (tetrahedral) whereas

In (Ni(CN)4)2- CN is strong field ligand which helps in pairing of electron thus 2 unpaired electrons of nickel are paired up due to which it becomes diamagnetic leading to configuration dsp2(square planar geometry)

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