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Q.

The geometry of Ni(CO)4  and [NiCl4]-2 are

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a

Tetrahedral and square planar 

b

Both tetrahedral 

c

Square planar and tetrahedral

d

Both square planar 

answer is C.

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Detailed Solution

Atomic number of Ni is 28 and its electronic configuration is:
[Ar]3d84s2
Oxidation number of Ni in NiCO4 is zero. So, sp3 orbitals of Ni is utilized in bonding with CO ligands in NiCO4. Therefore, geometry of NiCO4is tetrahedral.

Oxidation state of Ni is [NiCl4]-2 is +2 and its electronic configuration becomes
[Ar]3d8

As Cl is a weak ligand, therefore pairing of 3d electrons won't take place. So, sp3 orbitals of Ni is utilized in bonding with Cl ligands in [NiCl4]-2. Therefore, geometry of [NiCl4]-2 is tetrahedral. 

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