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Q.

 The geometry of Ni(CO)4 and NiPPh32Cl2 are 

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a

Tetrahedral, square planar

b

Both are square planar

c

Both are tetrahedral

d

Square planar, tetrahedral

answer is B.

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Detailed Solution

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In Ni(CO)4CO is a strong field ligand pairing of electrons in Ni atoms results sp3 hybridisation.

In NiPPh32Cl2 due to the bulky P Ph3 ligand it prefers sp3 hybridisation to minimize repulsions

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