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Q.

The Gibbs energy for the decomposition of Al2O3 at 500oC is as follows 

23Al2O343Al+O2           ΔrG=+966 kJ mol1

The potential difference needed for electrolytic reduction of Al2O3 at 500oC is at least 

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a

3.0 V

b

4.5 V

c

2.5 V

d

5.0 V

answer is C.

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Detailed Solution

23Al2O343Al+O2

Thus, 23×3(O2)

i.e., 2O2O2+4e[n=4]

ΔG=+966 kJ mol1=966×103 J mol1ΔG=nFEcell966×103=4×96500×EcellEcell=2.5V

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