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Q.

The Gibbs free energy of formation of MO and CO at temperature 1000°C and 1900°C are given below:

2M+O22MO                    G1000°C=-921KJ/mol                                                 G1900°C=-300KJ/mol 2C+O22CO                    G1000°C=-432KJ/mol                                                 G1900°C=-624KJ/mol

MO + C  M + CO 

This reaction is feasible at temperature : 

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a

1900°C

b

1000°C

c

900°C

d

1200°C

answer is A.

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Detailed Solution

Oxidation of C to CO has more VeG at 1900ºC. Than that of oxidation of M to MO at 1900ºC hence MO + C M + CO, is feasible at 1900ºC

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