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Q.

The group II reagent in the cation analysis is the dil.HCl + H2S. The role of dil.HCl is

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a

To decrease  S2and so increase the ionic product to exceed the KSp  of  group IV sulphides and prevent their precipitation.

b

To dissolve group II metal sulphides in acid medium

c

To decrease S2 concentration so that the  ionic product of  only  group II sulphides exceed  their Ksp  values

answer is A.

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Detailed Solution

H2S2H++S2,HClH++Cl
Due to common ion effect  H+S2decreases. KSpvalues of Group-II sulphides are less than Group-IV sulphides.  The decreased concentration is sufficient  to precipitate Gr-II cations, but not Group-IV cations.

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