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The group which deactivates the benzene ring towards the electrophilic substitution but directs the incoming group principally to o-and p-positions is

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$- {NH}_{2}$

$- {NO}_{2}$

$- C_{2} H_{5}$

$- Cl$

answer is D.

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Detailed Solution

Halogens are electron-withdrawing groups due to electronegative nature, hence they deactivate benzene ring for electrophilic substitution but are o,p-directing due to resonance. (As halogens have lone pair).

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