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Q.

The half cell reactions for the corrosion are, 
2H+12O2+2eH2OE0=1.23V    
 Fe+2+2eFesE0=0.44V
Find the  ΔG (in KJ) for the over all reaction. 
 

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a

76

b

322

c

161

d

152 

answer is B.

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Detailed Solution

FesFe+2+2e    ΔG

2H++2e+12O2H2Ol       ΔG2

Fes+2H++12O2Fe+2+H2O      ΔG3

Applying  ΔG1+ΔG2=ΔG3

ΔG3=2F×0.44+2F×1.23

=2×96500×0.44+2×96500×1.23

=322310J

=322kJ

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