Q.

The half-life period for the thermal decomposition of PH3 at three different pressures are given below :

Initial pressure (mm Hg)7077937.5
Half-life (seconds)848483

What is the order of the reaction?

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answer is 1.

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Detailed Solution

In first and second column,

P - 1

t1/2= same 

In second and third column

P - 2
t1/2= same

So, 

t1/2 of 1st order is independent of initial cone.

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