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Q.

The heat of neutralization of strong base and strong acid is 57.0 KJ. The heat released when 0.5 mole of HNO3  solution is added to 0.20 moles of NaOH  solution is

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a

28.5 KJ

b

34.9 KJ

 

c

57.0 KJ

d

11.40 KJ

answer is B.

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Detailed Solution

The reaction of neutralization of acid and base is given below:

H++OH-H2O+Heat  

From the reaction we can say that one mole of H+ reacts with one mole of OH- to give 57 kJ. When 0.5 moles of acid (HNO3) reacts with 0.2 moles of base, then 0.2 moles of neutralization will take place. 0.3 moles will remain unreacted. 

H+0.2 mole+OH-0.2 moleH2O

So, the heat evolved will be:

Heat=57×0.21=11.4 KJ 

Therefore, the correct option is B.

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