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Q.

The heat of reaction at constant volume for an exothermic reaction in equilibrium is 1200 cal more than that at constant pressure at 300 K. The ratio of Kp/Kc for the reaction is :

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a

2.77 x10-6

b

1.648x 10-3

c

606.6

d

1648

answer is D.

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Detailed Solution

ΔH=Δu+ΔnRTΔnRT=ΔuΔH=1200Δn=12002×300=2KpKc=(RT)Δn=(0.0821×300)2=1.648×103

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