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Q.

The heat of reaction for, 

C10H8(s)+12O2(g)10CO2(g)+4H2O(l), at constant volume is -122.2 k cal at 25°C. Calculate the heat of reaction at constant pressure at 25°C.

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answer is -1229.392.

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Detailed Solution

 For C10H8(s)+12O2(g)10CO2(g)+4H2O(1) Given, Δn=1012=2;ΔU=1228.2×103calT=298K;R=2cal ΔH=ΔU+ΔnRT=1228.2×103+(2)×2×298=1229392cal=1229.392kcal

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