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Q.

The heats of combustion of yellow P and red P are –9.91kJ and –8.78kJ respectively. The heat of transition of yellow to red phosphorus is

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a

+1.13 kJ

b

+18.69 kJ

c

–1.13 kJ

d

–18.69 Kj

answer is D.

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Detailed Solution

P(yellow) +52O2(g)12P2O5(s);ΔH1=9.91kJP(red )+52O2(g)12P2O5(s);ΔH2=8.78kJ
Rearranging, we get
P(yellow) +52O2(g)P2O5(g);ΔH=9.91kJP2O5P(red) +52O2(g);ΔH=+8.78kJ
Adding these two equations, we get
P(yellow )P(red );(9.91+8.78)kJ=1.13kJ

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