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Q.

The heats of neutralization of HCl with NH4OH and that of NaOH with CH3 COOH are respectively -51.4 and 1 50.6kJ eq-1 then the heat of neutralisation of acetic acid with  NH4OH will be

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a

44.6kJeq1

b

50.6kJeq1

c

51.4kJeq1

d

57.4kJeq1

answer is A.

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Detailed Solution

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HCl+NH4OH ;ΔH=51.4Hionisation =57.451.4=6kJNaOH+CH3COOH ΔH=50.6Hionization =57.450.6=6.8kJCH3COOH+NH4OH ΔH=57.4+6+6.8=44.6kJ

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