The highest H–C–H bond angle present in 

Due to electropositive character of hydrogen, electron density on carbon increases, so that bp-bp repulsions increase in CH₂. So CH₂ bond angle more than ${109}^{\circ }{28}^{\mathrm{\prime }}\text{ in }{\mathrm{CH}}_2{\mathrm{F}}_2$(113⁰)