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Q.

The hybrid state of B-atom in boron-hydride is sp2, while in its dimer it has sp3  hybrid state because :

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a

B2H6 is an electron rich compound

 

b

one of the empty orbitals of boron takes part in hybridisation

c

overlapping between s and p-orbitals of  H and B forms  π-bond

d

B2H6 is less stable than BH3

answer is A.

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Detailed Solution

Because it has three valence electrons, the element borax should make three bonds in a molecule (sp2) during hybridization because only the s and p orbitals are used, leaving the final p orbital unoccupied.
The diborane, on the other hand, contains two electrons per bond and three centre bonds. Each boron atom is joined by four hydrogen atoms. This leads to tetrahedral geometry.
As a result, every boron atom is sp3 hybridized.

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