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Q.

The hybridisation states of the central atom in the complexes [ Fe(CN)6]3-,

     [ Fe(CN)6]4- and [ Co(NO2)6]3- are 

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a

d2sp3, sp3d2 and d2sp3 respectively

b

d2sp3, sp3d2 and sp3d2 respectively

c

all d2sp3

d

d2sp3, sp3d2 and dsp2 respectively

answer is D.

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Detailed Solution

The central metal ions in the complexes [Fe(CN)6​]3−,[Fe(CN)6​]4−and[Co(NO2​)6​]3− undergo d2sp3 hybridization to form inner orbital complexes with octahedral geometry

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The hybridisation states of the central atom in the complexes [ Fe(CN)6]3-,     [ Fe(CN)6]4- and [ Co(NO2)6]3- are