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Q.

The hybridization and magnetic behaviour of cobalt ion in $[{[Co {({NH}_{3})}_{6}]}^{3 +}$ complex, respectively is

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a

$d^{2} {sp}^{3}$ and diamagnetic

b

$d^{2} {sp}^{3}$ and paramagnetic

c

${Sp}^{3} d^{2}$ and paramagnetic

d

${Sp}^{3} d^{2}$ and diamagnetic

answer is C.

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Detailed Solution

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${[Co {({NH}_{3})}_{6}]}^{3 +} {NH}_{3} = strong ligand .$
${CO}^{+ 3} : [Ar] 3 d^{6} 4 s^{0}$
Question Image

Diamagnetic [absence of unpaired electrons]

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The hybridization and magnetic behaviour of cobalt ion in CoNH363+ complex, respectively is