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Q.

The hybridization and magnetic nature of [Mn(CN)6]4 and [Fe(CN)6]3 , respectively are 

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a

d2sp3 and diamagnetic

b

sp3d2 and diamagnetic

c

 d2sp3 and paramagnetic

d

sp3d2 and paramagnetic

answer is C.

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Detailed Solution

[Mn(CN)6]4  and  [Fe(CN)6]3
  Mn2+                     Fe3+
   [Ar]3d54so         [Ar]3d54so 
Since,CNΘ is a strong field ligand and pairing will start and it will lead to formation of inner orbital complex 
Both will show same configuration
Question Image
d2sp3-hybridisation.
Due to unpaired electron it will be paramagnetic   
 

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