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Q.

The hybridization and magnetic nature of [Mn(CN)₆]^4- and [Fe(CN)₆]^3-, respectively are :

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a

sp³d² and diamagnetic

b

sp³d² and paramagnetic

c

d²sp³ and paramagnetic

d

d²sp³ and diamagnetic

answer is A.

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Detailed Solution

Question Image

The hybridization is : $d^{2} {sp}^{3}$

due to presence of one unpaired electron this complex is paramagnetic.

Question Image

The hybridization is : $d^{2} {sp}^{3}$

due to presence of one unpaired electron this complex is paramagnetic.

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The hybridization and magnetic nature of [Mn(CN)6]4- and [Fe(CN)6]3-, respectively are :