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Q.

The hybridization and unpaired electrons in [Fe(H2O)6]2+ ion are:
 

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a

 d2sp3; 3
 

b

 sp3d2; 2

c

 sp3d; 4

d

 sp3d2; 4 

answer is A.

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Detailed Solution

  • When two atomic orbitals join to generate a hybrid orbital in a molecule, the energy of the individual atoms' orbitals is redistributed to give orbitals of equivalent energy.
  • In the third orbital of [Fe(H2O)6]2+, there are 4 unpaired electrons. The hybridization and unpaired electrons in it are sp3d2 and 4 respectively. 

 

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