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Q.

The hybridizations of atomic orbitals of nitrogen in NO2+,NO3- and NH4+ respectively are

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a

sp2,sp3 and sp

b

sp,sp3 and sp2

c

sp,sp2 and sp3

d

sp2,sp and sp3

answer is C.

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Detailed Solution

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Number of Hybrid OrbitalsHybridisation
2sp
3sp2
4sp3
5sp3d
6sp3d2
7sp3d3

Number of hybrid orbitals = Number of Bpe+12 [Group number- Valency of central atom(Q)]
NO2+=2+12[541]=2=spNO3=3+12[56(1)]=3=sp2NH4+=4+12[541]=4=sp3
 

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The hybridizations of atomic orbitals of nitrogen in NO2+,NO3- and NH4+ respectively are