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Q.

The hydration of propyne in presence of dil. H2SO4/dil.HgSO4 results in formation of  

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a

Propene    

b

propan-1-ol

c

Propanal 

d

propanone

answer is B.

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Detailed Solution

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  • The hydration of an alkyne in the presence of dilute sulfuric acid and mercuric sulfate typically leads to the formation of a ketone via an intermediate enol, which rearranges to the more stable ketone.

 

  • Propyne (CH₃C≡CH), when hydrated, follows the Markovnikov rule, meaning that the -OH group will attach to the carbon with the most hydrogen atoms (the less substituted carbon of the alkyne), while the -H will add to the more substituted carbon.

 

  • This results in the formation of propanone (CH₃COCH₃), a ketone, after the initial formation of an enol intermediate, which tautomerizes to the more stable ketone.
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