Q.

The hydrogen electrode is dipped in a solution ofpH=3 at 250C. The potential of the cell would be (the value of 2.303 RT/F is 0.059 V)

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a

–0.177 V

b

0.059 V

c

0.087 V

d

0.177 V

answer is C.

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Detailed Solution

Here we have pH=3 i.e log1H+=3 and Ecell0=0.0V

Reaction will be,

H++e-12H2  ,  n=1

By Nernst equation

Ecell=Ecell0-0.0591nlog[H2]1/2[H+]

By putting values in equation we get

Ecell0=0-0.05911log1[H+]  

Ecell=-0.0591×3=-0.177V

Ecell=-0.177V

Hence option C is correct.

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