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Q.

The hydrolysis constant for the reaction. H2PO4+H2OH3PO4+OH   is 1.4×1012. The ionization constant for  H3PO4+H2OH2PO4+H3O+  is

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a

7.14×103

b

1.4×103

c

1.4×1012

d

7.14×1012

answer is A.

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Detailed Solution

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(A)  Kh=[H3PO4][OH][H2PO4]  &  Ka=[H2PO4][H3O+][H3PO4]
 Kh=[H3O+][OH]Ka=KwKa
 
Ka=KwKh=10141.4×1012=7.14×103

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