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Q.

The hypothetical reaction 2A+BC+D is catalyzed by E as indicated in the possible mechanism below. 

 Step 1: A+EAE (fast)

 Step 2:AE+AA2+E (slow)

 Step 3:A2+BC+D (fast)

Which rate law best agrees with this mechanism?

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a

 Rate =k[A][B]

b

 Rate =k[A][E]

c

 Rate =k[A]2[E]

d

 Rate =k[A]2[B]

answer is C.

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Detailed Solution

2A+BC+D

I A+E AE

keq=[AE][A[E]

II. Slow rate

AE +A A2+ E

r=k[AE][A]

=kKeq [A][E][A]

rateK1[A]2[E]

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