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The impossible set of quantum numbers is

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a
n = 2, l = 0, m = 0 , s = +1/2
b
n = 2, l = 1, m = 0 , s = +1/2
c
n = 2, l = 0, m = 1 , s = –1/2
d
n = 3, l = 1, m = -1 , s = –1/2

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detailed solution

Correct option is C

Permitted Values for quantum nubmers 

n= 1,2,3,...

l=0,1,...(n-1) .

m= -l ,..,0,...+l

For l=0 , m =1 NOT possible. 

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