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Q.

The impure $C H C l_{3}$ gives a white ppt when its treated with solution. $A g N O_{3}$ Its due to

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a

$C l_{2}$

b

$C O C l_{2}$

c

HCl

d

All

answer is C.

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Detailed Solution

Chloroform undergo oxidation and give a poisonous Phosgene along with HCl. The formed HCl reacts with $A g N O_{3}$

$C H C l_{3} + \frac{1}{2} O_{2} \to C O C l_{2} + H C l$

$\begin{array}{l} A g N O_{3} + H C l \to A g C l ↓ + H N O_{3} \\ w h i t e p p t \end{array}$

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