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Q.

The incorrect expression among the following is

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a

For isothermal process Wreversible =nR lnVfVi

b

In K=ΔHTΔSRT

c

ΔGSystem ΔSTotal =T( at constant P)

d

K=eΔG0/RT

answer is B.

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Detailed Solution

ΔG=ΔG+RT In Q
at equillibrium Q+Keq&ΔG=0
ΔG=RT In Keq
Keq=ΔG/RT    ΔG=HTΔS
From above equations
ΔHTΔS=RT In Keq  (or)  In Keq=ΔHTΔSRT=TΔSOHRT

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